Site errors: This section lists errors that prevent Googlebot from accessing your site at all.
URL errors: This section lists errors Googlebot encountered when trying to crawl specific URLs. You can search for specific URLs or errors. There are three tabs corresponding to three different Googlebot crawlers:
Web
for Googlebot, Google's main web crawler.
Smartphone
for Googlebot-Mobile for smartphones.
Feature Phone
for Googlebot-Mobile for feature phones.